Skin of Vash the stampede from Trigun. Wearing this will give you his mole on the left cheek, and the strapped outfit that he wears underneath his famous red coat.
The picture here is displayed with the boots, and the default bottoms your avatar is given when you remove all the bottoms you own. There is leg detail, such as metal kneecaps, which can be seen by wearing very short bottoms.

Click here to get the red coat.
Click here to get the red collar.
Click here to get the glasses.
Click here to get a pair of Vash boots.

Enjoy :)